{"id":3759,"date":"2024-04-12T12:04:34","date_gmt":"2024-04-12T09:04:34","guid":{"rendered":"https:\/\/nor-ijournal.com\/?p=3759"},"modified":"2024-04-18T17:37:30","modified_gmt":"2024-04-18T14:37:30","slug":"130-4","status":"publish","type":"post","link":"https:\/\/nor-ijournal.com\/ru\/2024\/04\/12\/130-4\/","title":{"rendered":"Aliyev I., Rahimova V., Ismailova S., Huseynova Sh., Iskendarova G. &#8211; PHYSICAL-CHEMICAL INVESTIGATION OF PHASE EQUILIBRIUM IN THE Cu3As4Te9-CrAsTe3 SYSTEM"},"content":{"rendered":"<div data-elementor-type=\"wp-post\" data-elementor-id=\"3759\" class=\"elementor elementor-3759\" data-elementor-settings=\"{&quot;ha_cmc_init_switcher&quot;:&quot;no&quot;}\">\n\t\t\t\t<div class=\"has_eae_slider elementor-element elementor-element-174423c e-flex e-con-boxed jltma-glass-effect-no wpr-particle-no wpr-jarallax-no wpr-parallax-no wpr-sticky-section-no wpr-column-slider-no wpr-equal-height-no e-con e-parent\" data-eae-slider=\"82938\" data-id=\"174423c\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;_ha_eqh_enable&quot;:false}\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"has_eae_slider elementor-element elementor-element-e289846 e-con-full e-flex jltma-glass-effect-no wpr-particle-no wpr-jarallax-no wpr-parallax-no wpr-sticky-section-no wpr-column-slider-no wpr-equal-height-no e-con e-child\" data-eae-slider=\"6305\" data-id=\"e289846\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;_ha_eqh_enable&quot;:false}\">\n\t\t\t\t<div class=\"elementor-element elementor-element-b5a0a35 jltma-glass-effect-no exad-sticky-section-no exad-glass-effect-no elementor-widget elementor-widget-heading\" data-id=\"b5a0a35\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<h2 class=\"elementor-heading-title elementor-size-default\">PHYSICAL-CHEMICAL INVESTIGATION OF PHASE EQUILIBRIUM IN THE Cu3As4Te9-CrAsTe3 SYSTEM<\/h2>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-863f119 jltma-glass-effect-no exad-sticky-section-no exad-glass-effect-no elementor-widget elementor-widget-text-editor\" data-id=\"863f119\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p style=\"text-align: right;\"><strong>Aliyev I.<br \/><\/strong><em>Doctor of Chemistry, prof. hands. lab.<br \/><\/em><strong>Rahimova V.<br \/><\/strong><em>Ph.D., Associate Prof.,<br \/><\/em><strong>Ismailova S.<br \/><\/strong><em>Researcher.<br \/><\/em><strong>Huseynova Sh.<br \/><\/strong><em>Ph.D. chemical sciences<br \/><\/em><em>Institute of Catalysis and Inorganic Chemistry named after M.F.Nagiyev,<br \/><\/em><em>Ministry of Science and Education of the Republic of Azerbaijan<br \/><\/em><strong>Iskendarova G.<br \/><\/strong><em>Ph.D. chemical sciences<br \/><\/em><em>Institute of Physics, Ministry of Science and<br \/><\/em><em>Education of the Republic of Azerbaijan<\/em><\/p><p><strong>Abstract<br \/><\/strong>The phase equilibrium in the Cu<sub>3<\/sub>As<sub>4<\/sub>Te<sub>9<\/sub>-CrAsTe<sub>3<\/sub> system was studied by methods of physicochemical analysis: differential thermal analysis (DTA), X-ray diffraction analysis (XRD), microstructural analysis (MSA), determination of density and microhardness, and a T-x phase diagram of the system was constructed. As a result, it was established that the phase diagram of the Cu<sub>3<\/sub>As<sub>4<\/sub>Te<sub>9<\/sub>-CrAsTe<sub>3<\/sub> system is a non-quasi-binary section of the quasi-ternary Cr<sub>2<\/sub>Te<sub>3<\/sub>-As<sub>2<\/sub>Te<sub>3<\/sub>-CuTe system. In the system at room temperature, solid solutions based on the Cu<sub>3<\/sub>As<sub>4<\/sub>Te<sub>9<\/sub> compound extends to 5 mol % CrAsTe<sub>3<\/sub>. The peritectic compound CrAsTe<sub>3<\/sub> decomposes as follows: CrAsTe\u2194M+Cr<sub>2<\/sub>Te<sub>3<\/sub>.<\/p><p><strong>\u00a0<\/strong><strong>Keywords:<\/strong> system, phase equilibrium, non-quasi-binary, diagram, density.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-206ce67 jltma-glass-effect-no exad-sticky-section-no exad-glass-effect-no elementor-widget elementor-widget-pdfjs_viewer\" data-id=\"206ce67\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"pdfjs_viewer.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<iframe data-src=\"https:\/\/nor-ijournal.com\/wp-content\/plugins\/pdf-viewer-for-elementor\/assets\/pdfjs\/web\/viewer.html?file=https:\/\/nor-ijournal.com\/wp-content\/uploads\/2024\/04\/NJD_130-15-18.pdf&amp;embedded=true\" style=\"display: block; margin-left: auto; margin-right: auto; width: 770px; height: 1045px;\" frameborder=\"1\" marginheight=\"0px\" 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elementor-element-5b319b8 e-flex e-con-boxed jltma-glass-effect-no wpr-particle-no wpr-jarallax-no wpr-parallax-no wpr-sticky-section-no wpr-column-slider-no wpr-equal-height-no e-con e-parent\" data-eae-slider=\"55779\" data-id=\"5b319b8\" data-element_type=\"container\" data-e-type=\"container\" data-settings=\"{&quot;_ha_eqh_enable&quot;:false}\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>","protected":false},"excerpt":{"rendered":"<p>PHYSICAL-CHEMICAL INVESTIGATION OF PHASE EQUILIBRIUM IN THE Cu3As4Te9-CrAsTe3 SYSTEM Aliyev I.Doctor of Chemistry, prof. hands. lab.Rahimova V.Ph.D., Associate Prof.,Ismailova S.Researcher.Huseynova Sh.Ph.D. chemical sciencesInstitute of Catalysis and Inorganic Chemistry named after M.F.Nagiyev,Ministry of Science and Education of the Republic of AzerbaijanIskendarova G.Ph.D. chemical sciencesInstitute of Physics, Ministry of Science andEducation of the Republic of Azerbaijan AbstractThe phase equilibrium in the Cu3As4Te9-CrAsTe3 system was studied by methods of physicochemical analysis: differential thermal analysis (DTA), X-ray diffraction analysis (XRD), microstructural analysis (MSA), determination of density and microhardness, and a T-x phase diagram of the system was constructed. As a result, it was established that the phase diagram of the Cu3As4Te9-CrAsTe3 system is a non-quasi-binary section of the quasi-ternary Cr2Te3-As2Te3-CuTe system. In the system at room temperature, solid solutions based on the Cu3As4Te9 compound extends to 5 mol % CrAsTe3. The peritectic compound CrAsTe3 decomposes as follows: CrAsTe\u2194M+Cr2Te3. \u00a0Keywords: system, phase equilibrium, non-quasi-binary, diagram, density. 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