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Mammadova Ay., Ahmadzada Z. – EFFECT OF MODİFİED ZEOLİTE CATALYSTS ON YİELD AND SELECTİVİTY OF ETHYLBENZENE

EFFECT OF MODİFİED ZEOLİTE CATALYSTS ON YİELD AND SELECTİVİTY OF ETHYLBENZENE

Mammadova Ay.
Doctor of Philosophy, Azerbaijan State Oil and Industry University
Ahmadzada Z.
Master Degree Student, Azerbaijan State Oil and Industry University

Abstract
Catalytic properties of ZSM-5 zeolite-based catalysts modified with cerium, magnesium, and yttrium were studied in a flow-through installation at atmospheric pressure in the temperature range of 350-500 °C. It is established that the nature of the modifier significantly affects the output and selectivity of the formation of ethylbenzene. Modification of HZSM-5 with modifiers reduces the yield of by-products and increases the yield and selectivity for ethylbenzene. The maximum yield and selectivity for ethylbenzene is achieved on the catalyst 4% Ce-HZSM-5, which is 38.3% and 58.8%, respectively.

 Keywords: Alkylation, benzene, ethanol, ethylbenzene, HZSM-5, modification, selectivity.